Having the link table is probably a better option. At least it does not violate normalization BCNF (Boyce-Codd normal form). however I would favor being pragmatic. If you have very few of these null values and they are only temporary I think you should skip the link table since it only adds complexity to the scheme.
On a side note; using a link table doesn't necessarily make it n to n, if you in the link table use the foreign key that's pointing to your orders table as the primary key in that link table the relationship is still 1..n. There can only be one entry in that link table per order.
